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IEP - Coal Utilization By-Products - Environmental Research
Characterization of Coal Combustion By-Products for Mercury

The objective of this work is to provide the necessary information to assess the impact of controlling Hg from coal-fired utilities by examining the materials resulting from coal combustion, which are either disposed of or utilized. This will be accomplished by:

  • Determining the Hg concentration in coal combustion waste streams, specifically bottom ash, fly ash, flue gas desulfurization sludge and solids (FGDS), and spray dryer solids (SDS)
  • Estimating percentage of Hg collected in the coal combustion waste streams based on the Hg in the as-fired coal
  • Determining if the Hg in the waste and by-product samples is leachable
  • Determining if the Hg in the waste and by-product samples is volatile
  • Evaluating the fate of Hg in coal fly ash in the manufacture of Portland cement
  • Evaluating the fate of Hg in FGD gypsum in the manufacture of wallboard
  • Evaluating the fate of Hg in the coal ash material used to make manufactured aggregate
  • Compiling a literature review of Hg chemistry and transformations in ecosystems
  • Evaluating the extent that Hg is leached and converted to methyl-mercury in sulfite sludge FGD landfill
  • Evaluating the extent that Hg is leached and converted to methyl-mercury in fly ash slurry impoundments

The results will be reported to DOE through a final report.

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